GR-846 dehydrogenator

GR-846 is a poisoning-resistant dehydrogenation catalyst designed for efficient hydrogen (H₂) removal in high-concentration carbon monoxide (CO) atmospheres. Conventional palladium-based catalysts are susceptible to deactivation due to CO adsorption in various industrial gases, such as coal gas and syngas. GR-846, through optimized active components and support design, significantly enhances its resistance to CO poisoning. It operates stably below the temperature at which CO disproportionates, achieving highly selective H₂ removal.
This catalyst boasts high activity, high mechanical strength, and excellent thermal stability. It is particularly suitable for deep purification of feed gases in processes such as DMF synthesis, coal-to-ethylene glycol, TDI, dimethyl oxalate, and dimethyl carbonate. It effectively improves downstream catalyst protection and product quality, extending plant operation cycles.

Product Description


Conventional Pd/Al203 dehydrogenators are prone to CO poisoning in high-concentration CO gas. H846 dehydrogenator has CO poisoning resistance and can remove hydrogen at a temperature far below the CO disproportionation reaction temperature.


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Working principle


2CO+02→2CO2    2H2+O2→2H₂


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Application areas


This GR-846 dehydrogenator has unique performance in resisting CO poisoning. It can be used for de hydrogenation of coal gas, synthesis gas, and high-concentration CO gas. It is especially suitable for de hydrogenation of raw gas such as synthetic DMF, coal-to- ethylene glycol, TDI, dimethyl oxalate, and dimethyl carbonate.


Product Parameters


appearance

Grey black spherical particles(pre-reduced)

granularity

φ3~5

Compressive strength, N/particle

≥50

loading density Kg/L

0.70~0.80

Operating temperature,℃

160~250

maneuvering speed

1000~2000

Using media

Industrial gases containing CO

Removal accuracy X10-5v/v

≤100


FAQ


1.Why do traditional Pd/Al₂O₃ catalysts easily deactivate in high CO atmospheres? How does GR-846 solve this problem?


Conventional catalysts are poisoned by strong CO adsorption on active sites, hindering the H₂ reaction. GR-846 modifies the active sites and support structure to reduce CO adsorption and enhance H₂ selective oxidation, maintaining high activity in CO-rich environments.


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2.What specific industrial scenarios is GR-846 applicable to?


It is particularly suitable for the dehydrogenation process of raw gas in processes such as synthesis gas, coal gas, and coal-to-ethylene glycol, DMF, TDI, dimethyl oxalate, and dimethyl carbonate. It can effectively remove H₂ and ensure the safety and reaction efficiency of catalysts in subsequent work sections.


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3.Does the catalyst need to be used within a specific temperature range?


Yes, GR-846 operates stably in a moderate temperature range and is typically below the temperature at which CO disproportionation occurs (2CO → C + CO₂), thus avoiding carbon deposition and maintaining long-term catalyst activity.


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4.What practical benefits can using GR-846 bring to customers?


Its main benefits include: reducing the frequency of catalyst replacement due to CO poisoning and lowering operating costs; improving product gas purity and protecting downstream precious metal catalysts; extending the unit operation cycle and improving overall production efficiency.


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5.Can this catalyst be used for dehydrogenation under oxygen-free or low-oxygen conditions?


No. This catalyst relies on oxygen as the oxidant for hydrogen and requires an oxygen-containing atmosphere to catalyze the dehydrogenation reaction. If the feed gas is oxygen-free, consider adding an appropriate amount of air or oxygen.


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